583041-49-0

Basic information

• Product Name: [(Z)-5-tert-butoxy-2-(dimethyl(phenyl)silyl)pent-2-enyl](dimethylcarbamoylmethyl)carbamic acid tert-butyl ester
• Synonyms: [(Z)-5-tert-butoxy-2-(dimethyl(phenyl)silyl)pent-2-enyl](dimethylcarbamoylmethyl)carbamic acid tert-butyl ester
• CAS NO: 583041-49-0
• Molecular Weight: 476.732
• Mol File: 583041-49-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [(Z)-5-tert-butoxy-2-(dimethyl(phenyl)silyl)pent-2-enyl](dimethylcarbamoylmethyl)carbamic acid tert-butyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: [(Z)-5-tert-butoxy-2-(dimethyl(phenyl)silyl)pent-2-enyl](dimethylcarbamoylmethyl)carbamic acid tert-butyl ester(583041-49-0)
• EPA Substance Registry System: [(Z)-5-tert-butoxy-2-(dimethyl(phenyl)silyl)pent-2-enyl](dimethylcarbamoylmethyl)carbamic acid tert-butyl ester(583041-49-0)

Safety Data

• Hazardous Substances Data: 583041-49-0(Hazardous Substances Data)

Upstream product

• 583041-59-2 (Z)-5-tert-butoxy-2-(dimethyl(phenyl)silyl)pent-2-en-1-ol 
• 583041-47-8 4-tert-butoxy-1-(dimethyl(phenyl)silyl)but-1-yne 
• 59574-66-2 4-tert-butoxybut-1-yne 
• 72287-76-4 N-[2-(dimethylamino)-2-oxoethyl]carbamic acid 1,1-dimethylethyl ester 
• 583041-48-9 [(Z)-1-bromomethyl-4-tert-butoxybut-1-enyl]dimethyl(phenyl)silane 

Downstream Products

• 487-79-6 (+/-)-α-kainic acid 

Relevant articles and documents

Total synthesis of (+/-)-kainic Acid with an aza-[2,3]-Wittig sigmatropic rearrangement as the key stereochemical determining step.

A flexible route to the kainoid skeleton is exemplified by the synthesis of (+/-)-kainic acid from 3-butyn-1-ol. The route relies on the aza-[2,3]-Wittig sigmatropic rearrangement to efficiently install the relative stereochemistry between C2-C3. The C4 s