58380-86-2Relevant academic research and scientific papers
Electrochemical synthesis of 2-aryl-2H-benzotriazoles and their N-oxides by controlled potential cathodic electrolysis
Kim, Byeong Hyo,Lee, Doo Byung,Kim, Dae Ho,Han, Rongbi,Jun, Young Moo,Baik, Woonphil
, p. 841 - 850 (2000)
Using a divided cell, reductive cyclizations of o-nitrophenylazo dyes (1) toward 2-aryl-2H-benzotriazole-1-oxides (2) or 2-aryl-2H-benzotriazoles (3) were successfully accomplished by the controlled potential cathodic electrolysis reactions. 1 was transformed to 2 under neutral conditions while 1 was transformed to 3 under basic conditions.
Pronounced conformational preference of the 3-α-cumyl substituent in 2-(2′-methoxy-3′-α-cumylphenyl)benzotriazole
Debellis, Anthony D.,Rodebaugh, Ronald K.,Suhadolnik, Joseph,Hendricks-Guy, Carmen
, p. 107 - 112 (2007/10/03)
A pronounced conformational preference of the 3′-α-cumyl substituent in 2-(2′-methoxy-3′-α-cumylphenyl)benzotriazole is suggested from the results of molecular dynamics simulations. This suggestion is supported by both solution NMR spectral and solid-state x-ray crystallographic data. The orientation of the α-cumyl substituent may have implications on the relative performance of 3′-substituted 2′-hydroxyphenylbenzotriazole light stabilizers in polar media.
Photooxidation of 2-Phenylbenzotriazoles
Amiet, R. Gary,Evans, Neil A.,Wynne, Paul M.
, p. 441 - 445 (2007/10/02)
Irradiation, with ultraviolet light, of 2-phenylbenzotriazole in aerated solvents resulted in oxidation of the benzo ring to yield the diacid 2-phenyl-1,2,3-tiazole-4,5-dicarboxylic acid.A possible intermediate, 2-phenylbenzotriazole-4,7-dione, also yielded the diacid on photooxidation.The methyl ether of the commercial photostabilizer Tinuvin P undergoes an analogous reaction to produce the corresponding diacid.
