58443-49-5Relevant academic research and scientific papers
Enantioselective intramolecular benzylic C-H bond amination: Efficient synthesis of optically active benzosultams
Ichinose, Masami,Suematsu, Hidehiro,Yasutomi, Yoichi,Nishioka, Yota,Uchida, Tatsuya,Katsuki, Tsutomu
supporting information; experimental part, p. 9884 - 9887 (2011/12/02)
'Salen' along: The iridium(III)-salen complex 1 efficiently catalyzes the title reaction of 2-ethylbenzenesulfonyl azides to give five-membered sultams with high enantioselectivity. Other 2-alkyl-substitued substrates lead to five- and six-membered sultam
