58547-47-0

Upstream product

• 691850-83-6 C₁₄H₂₆O₂Si 
• 17550-59-3 methyl α,β-epoxycyclohexanecarboxylate 

Relevant academic research and scientific papers

γ-oxygenation of α,β-unsaturated esters by vinylogous O-nitroso mukaiyama aldol reaction

A practical procedure has been developed for γ-oxygenation of α,β-unsaturated esters by a vinylogous O-nitroso Mukaiyama aldol reaction followed by a one-pot N-O bond heterolysis of the in situ generated γ-aminoxy-α,β-unsaturated esters.

Preparation of Allylic Alcohols from Epoxides Using Iodotrimethylsilane

The transformation of epoxides into allylic alcohols by use of iodotrimethylsilane and 1,5-diazabicycloundec-5-ene is described.The scope and limitations of this reaction are examined.This method is complementary to the method of Sharpless in the case of trisubstituted epoxides and proceeds under milder reaction conditions than the method employing lithium dialkylamides.