5859-49-4Relevant academic research and scientific papers
Allyl-, allenyl-, and propargyl-transfer reactions through cleavage of C-C bonds catalyzed by an n-heterocyclic carbene/copper complex: Synthesis of multisubstituted pyrroles
Sai, Masahiro,Yorimitsu, Hideki,Oshima, Koichiro
supporting information; scheme or table, p. 3294 - 3298 (2011/06/21)
Cat. in the bag: The pictured copper complex can promote C-C bond cleavage through retro-allylation of homoallyl alcohols to form allylcopper species. This process is applicable to catalytic allylation of aldehydes and imines with homoallyl alcohols. The method has also been extended to regioselective allenylation and propargylation of imines. Copyright
