58612-65-0Relevant academic research and scientific papers
EVIDENCE FOR PENTAALKYLPHOSPHORANE INTERMEDIATES IN THE REACTION OF DIENES AT THE BRIDGING PHOSPHORUS IN P-METHYLPHOSPHOLE DIMERS
Caster, Kenneth C.,Quin, Louis D.
, p. 5831 - 5834 (2007/10/02)
The rate of loss of the phosphorus atom in the 7-phosphanorbornene moiety of P-methyl phosphole dimers is greatly increased when the dimers are heated in the presence of 1,3-dienes.The major products are 3-phospholenes and 3a,7a-dihydrophosphindoles, formed in retrocycloaddition of the P(V) adduct of the diene and the phosphine.
