58636-76-3Relevant academic research and scientific papers
Electrolytic Partial Fluorination of Organic Compounds. 14. The First Electrosynthesis of Hypervalent Iodobenzene Difluoride Derivatives and Its Application to Indirect Anodic gem-Difluorination
Fuchigami, Toshio,Fujita, Toshiyasu
, p. 7190 - 7192 (1994)
The electrosynthesis of hypervalent iodobenzene difluorides was accomplished by anodic oxidation of p-nitro- and p-methoxyiodobenzenes with Et3N*3HF in anhydrous acetonitrile, and p-methoxyiodobenzene difluoride was used as a mediator for indirect anodic
Fluorocyclization of N-Propargyl Carboxamides by λ3-Iodane Catalysts with Coordinating Substituents
Takahashi, Shunsuke,Umakoshi, Yuki,Nakayama, Kaii,Okada, Yohei,Zhdankin, Viktor V.,Yoshimura, Akira,Saito, Akio
supporting information, p. 2997 - 3003 (2020/06/17)
Aiming at the enhanced catalytic activity of fluoro-λ3-iodane generated from iodoarene precatalyst with Selectfluor and HF?pyridine, this study focused on the λ3-iodanes bearing coordinating substituents. Compared to 4-iodoanisole as a precatalyst of our previous method, N-methyl-2-iodobenzamide or 2-iodobenzamide worked well in the fluorocyclization of N-propargyl carboxamides to oxazoles. Control experiments suggest the equilibrium mixture of iodane-amine complexes and cyclic iodane fluorides would be involved in the present catalysis. (Figure presented.).
Deconstructing the Catalytic, Vicinal Difluorination of Alkenes: HF-Free Synthesis and Structural Study of p-TolIF2
Sarie, Jér?me C.,Thiehoff, Christian,Mudd, Richard J.,Daniliuc, Constantin G.,Kehr, Gerald,Gilmour, Ryan
, p. 11792 - 11798 (2017/11/24)
Recently, contemporaneous strategies to achieve the vicinal difluorination of alkenes via an I(I)/I(III) catalysis manifold were independently reported by this laboratory and by Jacobsen and co-workers. Both strategies proceed through a transient ArI(III)
