5866-56-8Relevant articles and documents
Synthesis of pyrroles from benzyl isocyanoacetate
Lash,Bellettini,Bastian,Couch
, p. 170 - 172 (2007/10/02)
Benzyl esters of 5-unsubstituted pyrrole-2-carboxylic acids were prepared in excellent yields by the base-catalyzed condensation of benzyl isocyanoacetate with α-acetoxynitro compounds, or nitro-alkenes, in refluxing tetrahydrofuran. These pyrrolic products are important intermediates in the synthesis of porphyrins and related compounds.
Photoinduced Electron Transfer in Porphyrin-Quinone Cyclophanes, 6. - Porphyrin-Quinone Cyclophanes with Gradually Varied Acceptor Strength: Syntheses and Characterizations
Staab, Heinz A.,Weiser, Juergen,Futscher, Michael,Voit, Guido,Rueckemann, Andreas,Anders, Christine
, p. 2285 - 2302 (2007/10/02)
For studying intramolecular electron-transfer reactions, three groups of double- and single-bridged porphyrin-quinone cyclophanes 1-4, 5-9, and 11-14, resp., with gradual variation of quinone acceptor strengths were synthesized.As key intermediates for bu