58702-55-9

Upstream product

• 36078-93-0 2-[2-(4-methylphenyl)ethenyl]-1,3-benzothiazole 
• 15851-89-5 (E)-p-methylcinnamoyl chloride 
• 137-07-5 2-amino-benzenethiol 
• 1866-39-3 trans-p-methylcinnamic acid 
• 104-87-0 4-methyl-benzaldehyde 
• 120-75-2 2-Methylbenzothiazole 
• 1866-39-3 4-methylcinnamic acid 
• 35491-09-9 2-<2-(4-methylphenyl)ethenyl>-1,3-benzothiazole 

Downstream Products

• 60271-52-5 [4-(2-benzothiazol-2-yl-vinyl)-benzyl]-tris-(4-trifluoromethyl-phenyl)-phosphonium; bromide 
• 60271-51-4 [4-(2-benzothiazol-2-yl-vinyl)-benzyl]-diphenyl-(4-trifluoromethyl-phenyl)-phosphonium; bromide 
• 60271-46-7 [4-(2-benzothiazol-2-yl-vinyl)-benzyl]-bis-(4-dimethylamino-phenyl)-phenyl-phosphonium; bromide 
• 60271-45-6 [4-(2-benzothiazol-2-yl-vinyl)-benzyl]-tris-(4-dimethylamino-phenyl)-phosphonium; bromide 
• 142207-90-7 2-<2-<4-(dimethylphosphonatomethyl)phenyl>ethenyl>-1,3-benzothiazole 
• 58702-57-1 2-[4-(4-methyl-styryl)-styryl]-benzothiazole 
• 58702-56-0 2-[4-(4-nitro-styryl)-styryl]-benzothiazole 
• 58702-59-3 3-methyl-2-[4-(triphenylphosphonio-methyl)-styryl]-benzothiazolium; bis-(methyl sulfate) 
• 60271-68-3 2-(4-{[diphenyl-(4-trifluoromethyl-phenyl)-phosphonio]-methyl}-styryl)-3-methyl-benzothiazolium; bis-bromide 
• 60271-49-0 [4-(2-benzothiazol-2-yl-vinyl)-benzyl]-tri-p-tolyl-phosphonium; bromide 
• 60271-50-3 [4-(2-benzothiazol-2-yl-vinyl)-benzyl]-diphenyl-p-tolyl-phosphonium; bromide 

Relevant academic research and scientific papers

Synthesis, photophysical, electrochemical, and DSSC application of novel donor-acceptor triazole bridged dendrimers with a triphenylamine core and benzoheterazole as a surface unit

Triazole bridged novel donor-acceptor dendrimers with triphenylamine as the core and benzoheterazole as the surface unit have been synthesized by click chemistry via a convergent approach. All the dendrimers exhibited excellent optical and electrochemical

Synthesis and two-photon-excited fluorescence of benzothiazole-based compounds with various π-electron donors

We have synthesized a series of new D-π-A compounds that feature various electron donors and a fixed benzothiazolyl unit as an electron acceptor. The crystal structure of compound 3 [trans,trans-2-{4-[(4-N-carbazolyl)styryl]styryl}-1,3-benzothiazole, CSSB

Trivalent Boron as an Acceptor in Donor - π - Acceptor-Type Compounds for Single- and Two-Photon Excited Fluorescence

The synthesis, structure, and fluorescence properties of a series of new donor - π - acceptor (D - π - A) type compounds, with a trivalent boron, protected by two mesityl groups, as acceptor, and with various typical donors and different π-conjugated bridges, are reported. All these stable organoboron compounds show intense single-photon excited fluorescence (SPEF) and two-photon excited fluorescence (TPEF) in a wide spectral range from blue to green, with the spectral peak position of the SPEF being basically the same as that of the TPEF. The remarkably strong C-B(mesityl)2 bonding, and the well-conjugated π-system, shown in X-ray crystal structures of two compounds, indicate some charge transfer features of the ground state. Meanwhile, spectral data indicate that the charge transfer from donor to acceptor is greatly enhanced in the excited states. Based on typical structural data and comprehensive spectral data, the following structure - property relationships can be drawn: 1) the moderate arylamino donor can more effectively enhance the SPEF and TPEF intensities than can the strong alkylamino donor; 2) stilbene is a better π-bridge than styrylthiophene for its capability of enhancing and blue-shifting the SPEF and TPEF of the corresponding D - π - A compounds; and 3) when compared to its boron-free precursors and other analogues, -B(mesityl)2 invariably and consistently acts as an effective SPEF and TPEF fluorophore in all this series of organoboron compounds, which may result from its strong π -electron-withdrawing and charge transfer-inducing nature in the ground-state and, more dominantly, in the excited-state. Combining all the above positive structure factors, trans-4′-N,N-diphenylamino-4-dimesitylborylstilbene (compound 3) stands out as the optimized green SPEF and TPEF emitter. This compound exhibits an SPEF quantum yield φ of 0.91 at 522 nm in THF, a TPEF cross-section σ′ that is an order of magnitude larger than that of its boron-free precursor upon excitation by 800 nm femto-second laser pulses, and a two-photon absorption section a of 3.0 × 10-48 cm 4 s. In the blue light region, trans-4′ -N-carbazolyl-4-dimesitylborylstilbene (compound 4) shows significant SPEF and TPEF properties, with φ = 0.79 at 464 nm in THF and a large σ′ value, which is five times that of fluorescein upon excitation by 740 nm femto-second laser pulses.

Influence of the vinyl group on the calcium antagonistic activity of analogues of Fostedil

Four aryl vinyl diethyl benzylphosphonates related to Fostedil were synthesized and evalued for their in vitro calcium-inhibitory activity.None of these compounds exhibited any calcium antagonistic profile.Unlike a series of diethyl-styryl benzylphosphona