58705-86-5

Basic information

• Product Name: 1-Hexanol, 4-chloro-
• CAS NO: 58705-86-5
• Molecular Formula: C6H13ClO
• Molecular Weight: 136.622
• Mol File: 58705-86-5.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 1-Hexanol, 4-chloro-(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Hexanol, 4-chloro-(58705-86-5)
• EPA Substance Registry System: 1-Hexanol, 4-chloro-(58705-86-5)

Safety Data

• Hazardous Substances Data: 58705-86-5(Hazardous Substances Data)

Upstream product

• 111-27-3 hexan-1-ol 
• 82004-64-6 n-hexyl-hypochlorite 

Downstream Products

• 1003-30-1 2-ethyltetrahydrofuran 

Relevant articles and documents

OXIDATIVE δ-CHLORINATION OF ALIPHATIC ALCOHOLS IN THE SYSTEM LEAD TETRAACETATE- METAL CHLORIDE

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FERROUS ION INDUCED DECOMPOSITION OF ALKYL HYPOCHLORITES

The decomposition of primary, secondary and tertiary alkyl hypochlorites induced by ferrous and other one-electron oxidizable metal ions leads to δ-chloro alcohols in yields of 34-76percent.In decomposition of tertiary alkyl hypochlorites, β-fragmentation competes with intramolecular δ-chlorination.Tertiary cycloalkyl hypochlorites containing five- or six-membered rings undergo β-cleavage giving the corresponding ο-chloro ketones, while 1-methylcycloheptyl and 1-methylcyclooctyl hypochlorites by decomposition with ferrous ion proceed by transannular functionalization of δ-carbon atom and β-cleavage as a competing reaction.