58734-91-1Relevant academic research and scientific papers
Intermediates of thermal transformations of perfluoro-organic compounds. New spectral data and reactions
Buravtsev, Nikolay N.,A. Kolbanovsky, Yuly
, p. 35 - 42 (2007/10/03)
New completely fluorinated intermediates were identified from spectroscopic studies of thermal reactions of perfluoro-olefins, some carbocycles, and perfluoro-oxiranes in the gas phase. Detailed mechanisms of several complex reactions were established. For example, the mechanism of higher perfluoro-olefin synthesis from lower species under pyrolysis was established. Following this mechanism the first stage is the reversible reaction of biradicaloid formation which are isomeric to perfluoro-olefins. It was shown that biradicaloids are the primary intermediates in recombination of singlet completely fluorinated carbenes.
