58822-12-1 Usage
Description
(1-methylpyridin-4(1H)-ylidene)-N-oxomethanaminium chloride is a pyridinium salt compound with a chloro substituent, formed by the reaction of 1-methylpyridin-4(1H)-ylidene with N-oxomethanamine. This reaction results in a positively charged nitrogen atom and a chloride ion, giving the compound unique chemical properties and a wide range of potential applications.
Uses
Used in Organic Synthesis:
(1-methylpyridin-4(1H)-ylidene)-N-oxomethanaminium chloride is used as a reagent in organic synthesis for its unique chemical structure and properties. It aids in various chemical reactions, facilitating the formation of desired products and improving the efficiency of synthesis processes.
Used in Pharmaceutical Research:
In the pharmaceutical industry, (1-methylpyridin-4(1H)-ylidene)-N-oxomethanaminium chloride serves as a valuable reagent for the development of new drugs. Its unique properties make it useful in the synthesis of complex organic molecules, which can be further utilized in the creation of novel therapeutic agents.
Used in Catalysis:
(1-methylpyridin-4(1H)-ylidene)-N-oxomethanaminium chloride is employed as a catalyst in various chemical reactions. Its ability to facilitate and speed up reactions without being consumed in the process makes it a valuable tool in enhancing the efficiency of catalytic processes.
Used in Coordination Chemistry:
In coordination chemistry, (1-methylpyridin-4(1H)-ylidene)-N-oxomethanaminium chloride is used to form coordination complexes with metal ions. These complexes have potential applications in areas such as catalysis, materials science, and medicinal chemistry.
Used in Medical Research:
(1-methylpyridin-4(1H)-ylidene)-N-oxomethanaminium chloride is utilized in medical research for its potential applications in the development of new therapeutic agents and diagnostic tools. Its unique chemical properties make it a promising candidate for the study of various biological processes and the design of innovative medical solutions.
Check Digit Verification of cas no
The CAS Registry Mumber 58822-12-1 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 5,8,8,2 and 2 respectively; the second part has 2 digits, 1 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 58822-12:
(7*5)+(6*8)+(5*8)+(4*2)+(3*2)+(2*1)+(1*2)=141
141 % 10 = 1
So 58822-12-1 is a valid CAS Registry Number.
58822-12-1Relevant articles and documents
Spectroscopic and structural insights into N-substituted pyridinium-4-aldoximes and their pentacyanoferrate(II) complexes
Foreti?, Bla?enka,Picek, Igor,Damjanovi?, Vladimir,Cvijanovi?, Danijela,Puli?, Ivana,Kukovec, Boris-Marko,Matkovi?-?alogovi?, Dubravka
, p. 733 - 742 (2013)
Comparative kinetic and equilibrium studies on the formation and dissociation of three mono- and one bis-pyridinium-4-aldoxime pentacyanoferrate(II) complexes have been carried out in aqueous solutions at 25 °C and I = 0.1 M. The synthesis, spectroscopic and thermal characterization of a new N-methylpyridinium-4-aldoxime pentacyanoferrate(II) complex is presented. The obtained values for the equilibrium constants, identified as apparent formation constants (βf/M-1) along with kinetic parameters, the formation (kf/M-1 s-1) and dissociation (kd/s-1) rate constants indicated the behaving of all protonated pyridinium-4-aldoximes as weak π-acceptors. The pH-dependence of the dissociation rates has been analyzed in terms of ionization abilities of the coordinated ligands. The magnitude of the dissociation rates suggested that both protonated and deprotonated ligand forms are effective σ-donors that bind to the [Fe(CN)5]3- moiety through the nitrogen atom. The deprotonation of the coordinated aldoxime group leads to the reduced lability of the complexes due to increased σ-donor capability of aldoximato nitrogen causing the strengthened of the iron(II)-nitrogen bond. The values of dissociation activation parameters, ΔH? and ΔS?, are found to be consistent with the S N1 dissociative type of mechanism. The spectroscopic data (FT-IR, NMR and UV-Vis) of the isolated coordinated pentacyanoferrates(II) conforms with the weak π-acceptor properties of the pyridinium-4-aldoxime ligands. A detailed structural characterization of the iodide and chloride salt of N-methylpyridinium-4-aldoxime was also presented using NMR, FT-IR and UV-Vis spectroscopy, as well as X-ray diffraction.
