58824-35-4Relevant articles and documents
Conjugated Schiff's Bases. Part 12. Kinetics and Mechanism of Condensation of Active Methylene Derivatives (CH-Acids) with Nitrosobenzene
Moskal, Janusz,Milart, Piotr
, p. 3201 - 3215 (2007/10/02)
Condensation of various CH-acids of the beta-diketone-type with nitrosobenzene was found to involve a complex sequence of reactions including some reversible processes.The rate-limiting step exhibits second order kinetics and general base catalysis dependence.Structural and solvation effects were considered in terms of the corresponding activation parameters.A detailed mechanism for this condensation is proposed.