58879-39-3

Basic information

• Product Name: 1-Dodecen-3-one
• Synonyms: 3-oxo-1-dodecene;1-Dodecen-3-one
• CAS NO: 58879-39-3
• Molecular Formula: C12H22O
• Molecular Weight: 182.306
• Mol File: 58879-39-3.mol

Chemical Properties

• CAS DataBase Reference: 1-Dodecen-3-one(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Dodecen-3-one(58879-39-3)
• EPA Substance Registry System: 1-Dodecen-3-one(58879-39-3)

Safety Data

• Hazardous Substances Data: 58879-39-3(Hazardous Substances Data)

Upstream product

• 112-41-4 1-dodecene 

Downstream Products

• 65535-00-4 Dodecyl-3-mesyloxy-1-thiophenol 
• 83467-48-5 1-[(2R,4S,5R)-4-(tert-butyldiphenylsilanyloxy)-5-hydroxymethyltetrahydrofuran-2-yl]-5-methyl-1H-pyrimidine-2,4-dione 
• 75372-27-9 (2S,5R)-2-Hex-5-enyl-5-nonyl-pyrrolidine 
• 75372-27-9 (2R,5R)-2-Hex-5-enyl-5-nonyl-pyrrolidine 

Relevant articles and documents

Catalyse par le palladium at la lumiere ultra-violette de l'oxydation d'alcenes par l'oxygene moleculaire

The light-promoted oxidation of terminal alkenes by oxygen in the presence of catalytic amounts of palladium(II) complexes led to corresponding α,β-ethylenic carbonyl compounds and methyl ketones; rapid and extensive isomerisation of the starting alkene is observed.The effect of acetone as solvent on the efficiency of these oxidations is discussed.

PHOTOACTIVATION OF ALKENE OXIDATION BY MOLECULAR OXYGEN IN THE PRESENCE OF PALLADIUM

A catalytic cycle which leads to α-β ethylenic ketones and methyl ketones from terminal alkenes in the presence of palladium trifluoroacetate, oxygen and U.V. light is described.