5888-34-6

Basic information

• Product Name: bicyclo[2.2.1]heptane-2,7-diol
• Synonyms: bicyclo[2.2.1]heptane-2,7-diol
• CAS NO: 5888-34-6
• Molecular Formula: C₇H₁₂O₂
• Molecular Weight: 128.16898
• EINECS: 227-562-1
• Mol File: 5888-34-6.mol
• Article Data: 5

Chemical Properties

• Boiling Point: 300°C at 760 mmHg
• Flash Point: 153.6°C
• Appearance: /
• Density: 1.292g/cm³
• Vapor Pressure: 0.000114mmHg at 25°C
• Refractive Index: 1.59
• CAS DataBase Reference: bicyclo[2.2.1]heptane-2,7-diol(CAS DataBase Reference)
• NIST Chemistry Reference: bicyclo[2.2.1]heptane-2,7-diol(5888-34-6)
• EPA Substance Registry System: bicyclo[2.2.1]heptane-2,7-diol(5888-34-6)

Safety Data

• Hazardous Substances Data: 5888-34-6(Hazardous Substances Data)

Usage

InChI:InChI=1/C7H12O2/c8-6-3-4-1-2-5(6)7(4)9/h4-9H,1-3H2

Upstream product

• 498-66-8 norborn-2-ene 
• 498-66-8 norbornene 
• 478943-96-3 7-Acetyl-2-hydroxybicyclo<2.2.1>heptan 
• 844874-18-6 exo-2,3-epoxynorbornane 
• 13426-55-6 anti-7-acetoxybicyclo[2.2.1]hept-2-ene 
• 121-46-0 bicyclo[2.2.1]hepta-2,5-diene 
• 17290-01-6 (+/-)-5exo,7anti-diacetoxy-norborn-2-ene 
• 13426-52-3 syn-7-acetoxynorbornene 
• 31337-62-9 2-exo-bromonorbornan-7-syn-ol 
• 2979-27-3 (2RS,7SR)-2,7-diacetoxybicyclo<2.2.1>heptane 
• 4321-51-1 (+/-)-3exo-bromo-norbornane-2exo-ol 
• 4321-51-1 (+/-)-3endo-bromo-norbornane-2endo-ol 

Downstream Products

• 102473-97-2 (+/-)-2exo,7syn-bis-benzoyloxy-norbornane 
• 923-42-2 butane-1,2,4-tricarboxylic acid 
• 110-15-6 succinic acid 
• 2979-27-3 (2RS,7RS)-2,7-diacetoxybicyclo<2.2.1>heptane 
• 2979-27-3 (2RS,7SR)-2,7-diacetoxybicyclo<2.2.1>heptane 

Relevant articles and documents

Synthesis and characterization of norbornanediol isomers and their fluorinated analogues

Fluorinated norbornene monomers exhibit the requisite properties for inclusion in 157 nm photoresists, but traditional addition and radical polymerizations with these monomers have failed. Norbornanediols provide an alternate route to these materials via condensation polymerization, and methods have been developed for the efficient synthesis of the exo-2-syn-T- and endo-2-exo-3-dihydroxynorbornanes. Synthesis of the fluorinated analogues is complicated by steric and electronic effects; however, a high-yielding synthesis of endo-2-exo-3-dihydroxynorbornane bearing a 5-endo-[2,2-bis(trifluoromethyl) hydroxyethyl] substituent is reported.

DERMATOLOGICAL COMPOSITIONS AND METHODS

Disclosed are methods and compositions for regulating the melanin content of mammalian melanocytes; regulating pigmentation in mammalian skin, hair, wool or fur; treating or preventing various skin and proliferative disorders; by administration of various compounds, including alcohols, diols and/or triols and their analogues.

RUTHENIUM-CATALYZED OXIDATION OF 2,3-EPOXYNORBORNANE. INFLUENCE OF THE NATURE OF THE REOXIDIZING REAGENT.

The nature of the reoxidizing reagent plays a decisive role in the outcome of the ruthenium-catalyzed oxidation of 2,3-epoxynorbornane.