5897-56-3Relevant academic research and scientific papers
Reaction of Vinyl Sulphone with α-Metallated Nitriles
Agawa, Toshio,Yoshida, Yasuo,Komatsu, Mitsuo,Ohshiro, Yoshiki
, p. 751 - 755 (2007/10/02)
Vinyl sulphones (1) were subjected to nucleophilic addition by α-lithionitriles (2) and gave cyclized products, 3-oxothian 1,1-dioxides (3) or cyclopropane derivatives (4), in satisfactory yields according to the substituents on the reagents.The cyclopropanation reactions could be extended to the formation of cyclopropyl sulphides (12) - (16) in good yields.
