590361-99-2

Upstream product

• 20035-41-0 6-bromo-2-hydroxy-3-methoxybenzaldehyde 
• 590362-05-3 1-(3-benzyloxy-4-methoxy-2-triisopropylsilanyloxymethyl-phenyl)-3-isopropenyl-4-methyl-pent-3-en-1-ol 
• 590361-97-0 (2-benzyloxy-6-bromo-3-methoxy-benzyloxy)-triisopropyl-silane 
• 590361-96-9 2-benzyloxy-6-bromo-3-methoxybenzyl alcohol 
• 159263-87-3 2-acetyloxy-3-methoxy-6-bromobenzaldehyde 
• 113250-72-9 2-benzyloxy-6-bromo-3-methoxybenzaldehyde 
• 148-53-8 3-methoxy-2-hydroxybenzaldehyde 
• 100-44-7 benzyl chloride 
• 590361-98-1 [2-benzyloxy-6-(3-isopropenyl-1-methoxy-4-methyl-pent-3-enyl)-3-methoxy-benzyloxy]-triisopropyl-silane 

Downstream Products

• 590362-01-9 1-[2-benzyloxy-6-(3-isopropenyl-1-methoxy-4-methyl-pent-3-enyl)-3-methoxy-phenyl]-propenone 
• 590362-06-4 1-[2-benzyloxy-6-(3-isopropenyl-1-methoxy-4-methyl-pent-3-enyl)-3-methoxy-phenyl]-prop-2-en-1-ol 
• 590362-00-8 2-benzyloxy-6-(3-isopropenyl-1-methoxy-4-methyl-pent-3-enyl)-3-methoxy-benzaldehyde 

Relevant academic research and scientific papers

A stereoselective intramolecular Diels-Alder strategy for the tricyclo[9.3.1.03,8]pentadecane core of aromatic C-ring taxanes

A stereoselective Lewis acid-catalyzed and chelation controlled intramolecular Diels-Alder entry into the tricyclo[9.3.1.03,8]pentadecane core of aromatic C-ring taxanes is described. The approach affords an efficient, high yield, access to aromatic C-ring taxanes variably functionalized at the C2, C4, C5, and C9 positions.