59100-01-5

Basic information

• Product Name: methyl 4-((12-hydroxydodecyl)oxy)benzoate
• Synonyms: methyl 4-((12-hydroxydodecyl)oxy)benzoate
• CAS NO: 59100-01-5
• Molecular Weight: 336.472
• Mol File: 59100-01-5.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: methyl 4-((12-hydroxydodecyl)oxy)benzoate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 4-((12-hydroxydodecyl)oxy)benzoate(59100-01-5)
• EPA Substance Registry System: methyl 4-((12-hydroxydodecyl)oxy)benzoate(59100-01-5)

Safety Data

• Hazardous Substances Data: 59100-01-5(Hazardous Substances Data)

Upstream product

• 5675-51-4 1,12-dodecandiol 
• 73367-80-3 12-bromododecanoic acid 
• 3344-77-2 12-bromododecanol 
• 99-76-3 methyl 4-hydroxylbenzoate 

Downstream Products

• 1206167-86-3 C₆₁H₇₂O₁₂ 
• 112231-71-7 4-((12-hydroxydodecyl)oxy)benzoic acid 
• 112231-57-9 4-((12-(acryloyloxy)dodecyl)oxy)benzoic acid 
• 59100-15-1 4-(12-Acetylsulfanyl-dodecyloxy)-benzoic acid methyl ester 
• 59100-64-0 4-(12-Mercapto-dodecyloxy)-benzoic acid 
• 59100-08-2 4-(12-Methanesulfonyloxy-dodecyloxy)-benzoic acid methyl ester 
• 1353086-76-6 C₇₄H₈₈F₂O₁₂S₂ 
• 1353086-75-5 C₆₆H₇₆F₂O₁₁ 
• 1353086-74-4 C₇₁H₈₄F₂O₁₂ 
• 1202651-63-5 4-(12-(tetrahydro-2H-pyran-2-yloxy)dodecanyloxy)benzoic acid 
• 1202651-62-4 methyl 4-(12-(tetrahydro-2H-pyran-2-yloxy)dodecyloxy)benzoate 

Relevant articles and documents

The first blue phase reactive monomers containing a bi-mesogenic core and their side-chain polymers

Two novel blue phase (BP) reactive monomers M1 and M2 containing a bi-mesogenic core are first reported by introducing two end-attached acrylic spacers with different lengths. Due to the self-assembly of bi-mesogenic cores with the same side-by-side end-attached acrylate spacers in homopolymers P1 and P2, no blue phase could be induced by homopolymerization of M1 and M2. However, by interrupting the self-assembly of bi-mesogenic cores with different side-by-side spacer lengths of copolymers P12, double-twisted cylinders of BPIII could be further extended by copolymerization of M1 and M2 with different molar ratios. With M1:M2 = 5:5 (molar ratio) in both side-chain copolymers P12(soln:5/5) and P12(photo:5/5) rather than binary mixture M1/M2(5/5), the widest BPIII ranges of 5.3 °C and 3.8 °C could be obtained by solution- and photo-polymerization, respectively.

Novel supramolecular side-chain banana-shaped liquid crystalline polymers containing covalent- and hydrogen-bonded bent cores

Novel supramolecular side-chain banana-shaped liquid crystalline (LC) polymer complexes AmBn-N bearing various (m/n) molar ratios of hydrogen- and covalent-bonded bent-core components were acquired by the free radical polymerization, where the hydrogen-bonded (H-bonded) structures were executed via mixing equimolar portions of proton donor (H-donor) polymers AmBn (homopolymers/ copolymers) and pyridyl proton acceptor (H-acceptor) bent cores (small molecules). The influences of the molar ratios of bent-core H-bonded components in side-chain banana-shaped LC polymers and their corresponding polymer complexes on mesomorphic and electro-optical properties were first investigated, The voltage-dependent antiferroelectric properties of spontaneous polarization (Ps) values in the polar smectic phase of the supramolecular side-chain banana-shaped copolymers were also reported. The nematic and tilted smectic phases were verified by XRD measurements, and the SmCP phase was further confirmed by the triangular wave method. Surprisingly, a novel enantiotropic polar smectic (SmCPA) phase was generated in some bent-core side-chain polymer complexes AmBn-N. Therefore, a special approach to constructing (or stabilizing) the SmCP phase was first developed in this study by copolymerization of bent-core covalent- and H-bonded units in side-chain polymer complexes (with proper m/n molar ratios of 16/1 and 10/1) from both bent-core covalent- and H-bonded monomers (i.e., B and A-N units, respectively) without the SmCP phase.