59129-92-9Relevant academic research and scientific papers
Solvent-free syntheses of salicylaldimines assisted by microwave irradiation
Yang, Haijian,Sun, Wen-Hua,Li, Zilong,Wang, Leyong
, p. 2395 - 2402 (2002)
A microwave-assisted condensation of salicylaldehyde and aryl amines without solvent were efficiently performed to form a series of salicylaldimines in high yields, which were confirmed by IR, 1H NMR, 13C NMR and elemental analyses. The microwave-assisted condensation provided a convenient environmental-friendship methodology for syntheses of Schiff-base in organic syntheses.
Studies on Dioxouranium(VI) Complexes with some Schiff Bases
Prabhu, P. S.,Dodwad, S. S.
, p. 475 - 478 (2007/10/02)
Uranyl complexes of some Schiff bases obtained by condensing salicylaldehyde with 2-aminopyridine, aniline and nitroanilines and 5-methylsalicylaldehyde with 2-aminopyridine are synthesized and characterised by elemental analysis, spectral and conductance data and magnetic susceptibility study.All the complexes are orange-red in colour, microcrystalline in nature and from compounds of the type (NO3)2 and , where LH and L are Schiff base molecules, L representing the ligand containing pyridyl nitrogen in the structure.The bonding with the metal in the complexes takes place from oxygen and hydroxyl oxygen in the two types of ligands and the imine nitrogen of the ligands.Pyridyl nitrogen does not take part in coordination.The studies show that the complexes formed are 1:2 adducts and that the complexes have coordination number eight and six, respectively.
