591721-39-0

Basic information

• Product Name: 1,3-Butanediol, 2-bromo-4-[(S)-(4-methylphenyl)sulfinyl]-1-phenyl-, (1R,2R,3S)-
• CAS NO: 591721-39-0
• Molecular Formula: C17H19BrO3S
• Molecular Weight: 383.306
• Mol File: 591721-39-0.mol

Chemical Properties

• CAS DataBase Reference: 1,3-Butanediol, 2-bromo-4-[(S)-(4-methylphenyl)sulfinyl]-1-phenyl-, (1R,2R,3S)-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3-Butanediol, 2-bromo-4-[(S)-(4-methylphenyl)sulfinyl]-1-phenyl-, (1R,2R,3S)-(591721-39-0)
• EPA Substance Registry System: 1,3-Butanediol, 2-bromo-4-[(S)-(4-methylphenyl)sulfinyl]-1-phenyl-, (1R,2R,3S)-(591721-39-0)

Safety Data

• Hazardous Substances Data: 591721-39-0(Hazardous Substances Data)

Upstream product

• 95482-76-1 (R,E)-4-phenyl-1-(p-tolylsulfinyl)but-3-en-2-one 
• 651358-94-0 (Rs)-2-tert-butyldimethylsilyloxy-4-phenyl-(2R,3E)-3-butenyl 4-methylphenyl sulfoxide 
• 651358-95-1 2-bromo-3-tert-butyldimethylsilyloxy-(4Ss)-(4-methylphenylsulfinyl)-1-phenyl-(1R,2R,3S)-butan-1-ol 
• 95482-80-7 1-(4-methylphenylsulfinyl)-4-phenyl-(2R,3E)-3-buten-2-ol 

Downstream Products

• 591721-41-4 5-azido-2,2-dimethyl-(S_S)-4-(4-methylphenylsulfinylmethyl)-6-phenyl-(4S,5R,6R)-1,3-dioxane 
• 591721-44-7 methyl 5-azido-2,2-dimethyl-6-phenyl-(4R,5S,6R)-1,3-dioxane-4-carboxylate 
• 591721-43-6 5-azido-2,2-dimethyl-6-phenyl-(4R,5S,6R)-1,3-dioxan-4-ylmethanol 
• 591721-45-8 methyl 3-azido-2,4-dihydroxy-4-phenyl-(2R,3S,4R)-butanoate 
• 116565-10-7 (2R,3S)-N-(tert-butoxycarbonyl)-3-amino-2-hydroxy-4-phenylbutanoic acid methyl ester 
• 591721-40-3 5-bromo-2,2-dimethyl-(S_S)-4-(4-methylphenylsulfinylmethyl)-6-phenyl-(4S,5R,6R)-1,3-dioxane 

Relevant articles and documents

A novel and stereospecific synthesis of (+)-preussin

A novel and stereospecific approach to (+)-preussin that would permit the synthesis of analogs for structure activity relationship studies, is disclosed. The key step includes the regio- and stereoselective elaboration of a bromohydrin via intramolecular sulfinyl group participation.

Sulfinyl moiety as an internal nucleophile. Part 6: Stereospecific synthesis of 3-amino-2-hydroxy-4-phenylbutanoate

A novel and stereospecific synthesis of (2R,3S)-3-amino-2-hydroxy-4-phenylbutanoate (AHPBA) is disclosed. The key step includes regio- and stereospecific functionalization of an alkene by the pendant sulfinyl group.

Stereoselective bromohydrin formation from β-hydroxy sulfoxides mediated by the pendant sulfoxide

Regio- and stereo-selective bromohydrin formation promoted by a neighbouring sulfinyl moiety is disclosed.