591766-29-9

Basic information

• Product Name: 2-Pentanone, 1-diazo-4-methyl-1-phenyl-
• CAS NO: 591766-29-9
• Molecular Formula: C12H14N2O
• Molecular Weight: 202.256
• Mol File: 591766-29-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 2-Pentanone, 1-diazo-4-methyl-1-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Pentanone, 1-diazo-4-methyl-1-phenyl-(591766-29-9)
• EPA Substance Registry System: 2-Pentanone, 1-diazo-4-methyl-1-phenyl-(591766-29-9)

Safety Data

• Hazardous Substances Data: 591766-29-9(Hazardous Substances Data)

Upstream product

• 5349-62-2 4-Methyl-1-phenyl-2-pentanone 

Downstream Products

• 1114883-74-7 1-((1S,2R)-1,2-diphenylcyclopropyl)-2-methylbutan-1-one 

Relevant articles and documents

Enantioselective Synthesis of 2,2,3-Trisubstituted Indolines via Bimetallic Relay Catalysis of α-Diazoketones with Enones

An efficient asymmetric intramolecular trapping of ammonium ylides of α-diazoketones with enones to synthesize indoline derivatives was realized. A Rh(II)/chiral N,N′-dioxide-Sc(III) complex bimetallic relay catalytic system was established. A series of optically active 2,2,3-trisubstituted indolines were obtained in high yields (up to 99%), good enantioselectivities (up to 99% ee), and excellent diastereoselectivities (up to >19:1 dr) under mild reaction conditions.