59184-24-6Relevant academic research and scientific papers
A new stereospecific method for 1,2-cis-glycosylation
Kochetkov, Nicolay K.,Klimov, Evgeny M.,Malysheva, Nelly N.,Demchenko, Alexey V.
, p. 77 - 91 (2007/10/02)
A new stereospecific method for 1,2-cis-glycosylation involves the reaction of 1,2-trans-glycosyl thiocyanates with sugar trityl ethers in the presence of triphenylmethylium perchlorate.The method has been applied to give disaccharide derivatives with (1->6), (1->4), (1->3), and (1->2) linkages.
NOVEL HIGHLY STEREOSPECIFIC METHOD OF 1,2-CIS-GLYCOSYLATION. SYNTHESIS OF α-D-GLUCOSYL-D-GLUCOSES
Kochetkov, Nikolay K.,Klimov, Evgeny M.,Malysheva, Nelly N.
, p. 5459 - 5462 (2007/10/02)
Triphenylmethylium perchlorate-catalysed glycosylation of 2-, 3-, 4-, and 6-O-trityl-D-glucose derivatives with β-D-glucopyranosyl thiocyanates bearing a nonparticipating substituent at O-2 affords stereospecific derivatives of α-D-glucosyl-D-glucose
