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CAS

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592531-07-2

2-Oxazolidinone, 4-(hydroxymethyl)-3-[(1R)-1-phenylethyl]-, (4R)- is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 592531-07-2 Structure

  • Basic information

    1. Product Name: 2-Oxazolidinone, 4-(hydroxymethyl)-3-[(1R)-1-phenylethyl]-, (4R)-
    2. Synonyms:
    3. CAS NO:592531-07-2
    4. Molecular Formula: C12H15NO3
    5. Molecular Weight: 221.256
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 592531-07-2.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: 2-Oxazolidinone, 4-(hydroxymethyl)-3-[(1R)-1-phenylethyl]-, (4R)-(CAS DataBase Reference)
    10. NIST Chemistry Reference: 2-Oxazolidinone, 4-(hydroxymethyl)-3-[(1R)-1-phenylethyl]-, (4R)-(592531-07-2)
    11. EPA Substance Registry System: 2-Oxazolidinone, 4-(hydroxymethyl)-3-[(1R)-1-phenylethyl]-, (4R)-(592531-07-2)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 592531-07-2(Hazardous Substances Data)

592531-07-2 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 592531-07-2 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 5,9,2,5,3 and 1 respectively; the second part has 2 digits, 0 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 592531-07:
(8*5)+(7*9)+(6*2)+(5*5)+(4*3)+(3*1)+(2*0)+(1*7)=162
162 % 10 = 2
So 592531-07-2 is a valid CAS Registry Number.

592531-07-2Relevant articles and documents

Studies on two different diastereoselective reaction pathways from a serinol derivative to 4-hydroxymethyl-2-oxazolidinones using 2-chloroethyl chloroformate and N,N′-disuccinimidyl carbonate

Sugiyama, Shigeo,Ishii, Keitaro

scheme or table, p. 2904 - 2910 (2011/03/19)

Two reaction pathways and their diastereoselectivity-determining steps of the asymmetric desymmetrization of (R)-2-(α-methylbenzyl)amino-1,3- propanediol 1 with 2-chloroethyl chloroformate (CCF) and with N,N′-disuccinimidyl carbonate giving (4S,αR)-4-hydr

Diastereoselective intramolecular acyl transfer of 5-(α-methylbenzyl)amino-1,3-dioxan-2-one to 4-hydroxymethyl-2-oxazolidinones

Sugiyama, Shigeo,Fukuchi, Haruka,Ishii, Keitaro

, p. 12047 - 12057 (2008/03/13)

Intramolecular acyl transfer of (R)-5-(α-methylbenzyl)amino-1,3-dioxan-2-one (2) by treatment with DBU in CD2Cl2, CDCl3, C6D6, CD3CN, CD3NO2, DMSO-d6, DMF,

A novel dynamic kinetic resolution accompanied by intramolecular transesterification: Asymmetric synthesis of a 4-hydroxymethyl-2-oxazolidinone from serinol derivatives

Sugiyama, Shigeo,Watanabe, Shoko,Inoue, Takayuki,Kurihara, Rie,Itou, Takahiro,Ishii, Keitaro

, p. 3417 - 3425 (2007/10/03)

Reaction paths of the one-pot reaction of (R)-2-(α-methylbenzyl)amino-1,3-propanediol (1) and 2-chloroethyl chloroformate with DBU giving (4S,αR)-4-hydroxymethyl-3-(α-methylbenzyl)-2-oxazolidinone [(4S)-2] (94% de) were investigated. Intermediates of this reaction, 2-chloroethyl (2S)- and 2-chloroethyl (2R)-3-hydroxy-2-[(αR)-α-methylbenzyl]aminopropyl carbonates [(2S)-4 and (2R)-4], were synthesized individually. After the addition of DBU to the respective solution of the carbonate (2S)-4 and that of (2R)-4 in dichloromethane, the intramolecular transesterification between (2S)-4 and (2R)-4 and the diastereoselective intramolecular cyclization proceeded to afford (4S)-2 in high diastereomeric excess. Therefore, two monocarbonates (2S)-4 and (2R)-4 were kinetically resolved by this cyclization during the intramolecular transesterification between (2S)-4 and (2R)-4. We found that this process involved dynamic kinetic resolution accompanied by intramolecular transesterification.

One-pot acylation and fractional crystallization: Preparation of optically active serinol monobenzoates

Sugiyama, Shigeo,Inoue, Takayuki,Ishii, Keitaro

, p. 2153 - 2160 (2007/10/03)

Mono-O-acylation of (R)-2-(α-methylbenzyl)amino-1,3-propanediol 1 with 4-nitrobenzoyl chloride and DMAP in dichloromethane at room temperature gave crystals of optically active (2S,αR)-3-hydroxy-2-(α-methylbenzyl)aminopropyl 4-nitrobenzoate hydrochloride

Asymmetric synthesis of the 4-hydroxymethyl-2-oxazolidinone from the serinol derivative and chloroformates

Sugiyama, Shigeo,Watanabe, Shoko,Ishii, Keitaro

, p. 7489 - 7492 (2007/10/03)

Asymmetric desymmetrization of 2-[(αR)-α-methylbenzyl]amino-1,3-propanediol (1) with 2-chloroethyl chloroformate and DBU at room temperature gave optically active (4S)-4-hydroxymethyl-N-[(αR)-α-methylbenzyl]-2-oxazolidinone [(4S)-2] (up to 94% de). This r

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