592533-01-2

Upstream product

• 10387-40-3 potassium thioacetate 
• 592533-00-1 3-C-(2,3,6-tri-O-benzyl-α-D-galactopyranosyl)propene 
• 592532-99-5 (2S,4aR,6R,7S,8R,8aS)-6-Allyl-7,8-bis-benzyloxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxine 
• 592532-98-4 (2S,4aR,6R,7R,8R,8aR)-6-Allyl-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxine-7,8-diol 
• 133697-14-0 2,6-anhydro-7,8,9-trideoxy-D-glycero-L-galacto-non-8-enitol 
• 53263-18-6 allyl 2,3,4,6-tetra-O-acetyl-α-D-galactopyranoside 

Downstream Products

• 592533-02-3 Thioacetic acid S-[(2R,3R,4R,5S,6R)-4,5-bis-benzyloxy-2-benzyloxymethyl-6-(2-oxo-ethyl)-tetrahydro-pyran-3-yl] ester 

Relevant academic research and scientific papers

Synthesis of thio-C-glycosides from 2′-carbonylalkyl C-glycosides by a tandem β-elimination and intramolecular hetero-Michael addition

2′-Carbonyl 5-S-acetyl-C-glycofuranosides and 2′-carbonyl 4-S-acetyl-C-glycopyranosides were converted in good yields to respective 5-thio-C-glycopyranosides and 4-thio-C-glycofuranosides under base treatment. The transformation was resulted from β-elimin