593-09-9Relevant academic research and scientific papers
A dehydrohalogenation methodology for synthesizing terminal olefins under mild conditions
Berube, Marie,Kamal, Fatima,Roy, Jenny,Poirier, Donald
, p. 3085 - 3091 (2008/02/08)
A new methodology for preparing terminal olefins in good yield by dehydrohalogenation of primary alkyl iodide with tetrabutylammonium fluoride in dimethyl sulfoxide at room temperature is presented. Optimization of the mild reaction conditions and assays on various alkyl iodides are described. Georg Thieme Verlag Stuttgart.
Electrochemical fluorodeiodination of alkyl iodides
Sawaguchi, Masanori,Ayuba, Shinichi,Nakamura, Yutaka,Fukuhara, Tsuyoshi,Hara, Shoji,Yoneda, Norihiko
, p. 999 - 1000 (2007/10/03)
Electrochemical oxidation of alkyl iodides using Et3N-nHF complexes as an electrolyte proceeds under mild conditions to give alkyl fluorides in good yields. The reaction is highly chemoselective and the functional groups in the substrate such as an ester, ketone, chloride, and tosylate could be tolerated under the reaction conditions.
