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1,4-Hexadien-3-one, 1-(trimethylsilyl)-, (E,E)- is a chemical compound with the molecular formula C9H18OSi. It is an organic compound that features a hexadienone core with a trimethylsilyl group attached to the carbonyl carbon. The (E,E)- configuration indicates that both double bonds in the molecule have the same geometric arrangement, with the substituents on each double bond being on the same side of the molecule. 1,4-Hexadien-3-one, 1-(trimethylsilyl)-, (E,E)- is often used in organic synthesis as a protecting group for carbonyl compounds and as a reagent in various chemical reactions. It is also known for its applications in the synthesis of complex organic molecules and as a precursor in the production of pharmaceuticals and other specialty chemicals.

59376-60-2

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59376-60-2 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 59376-60-2 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 5,9,3,7 and 6 respectively; the second part has 2 digits, 6 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 59376-60:
(7*5)+(6*9)+(5*3)+(4*7)+(3*6)+(2*6)+(1*0)=162
162 % 10 = 2
So 59376-60-2 is a valid CAS Registry Number.

59376-60-2SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 14, 2017

Revision Date: Aug 14, 2017

1.Identification

1.1 GHS Product identifier

Product name 1-trimethylsilylhexa-1,4-dien-3-one

1.2 Other means of identification

Product number -
Other names 1,4-Hexadien-3-one,1-(trimethylsilyl)

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:59376-60-2 SDS

59376-60-2Downstream Products

59376-60-2Relevant academic research and scientific papers

Silicon-Directed Nazarov Reactions II. Preparation and Cyclization of β-Silyl-substituted Divinyl Ketones

Jones, Todd K.,Denmark, Scott E.

, p. 2377 - 2396 (2007/10/02)

Two general methods for the preparation of β-silyl-substituted divinyl ketones have been developed starting from either α,β-unsaturated aldehydes or simple ketones.Anhydrous FeCl3 induces the cyclization to cyclopentenones under mild conditions and in good yields with predictable and complete control over the position of the double bond in the five-membered ring.The observed effects of substituents on rate can be explained by a rate-determining cationic electrocyclization.Silyl substitution has been shown to retard the reaction.

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