59415-76-8

Basic information

• Product Name: trans-1,4-dimethoxy-2-cyclohexene
• Synonyms: trans-1,4-dimethoxy-2-cyclohexene
• CAS NO: 59415-76-8
• Molecular Weight: 142.198
• Mol File: 59415-76-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: trans-1,4-dimethoxy-2-cyclohexene(CAS DataBase Reference)
• NIST Chemistry Reference: trans-1,4-dimethoxy-2-cyclohexene(59415-76-8)
• EPA Substance Registry System: trans-1,4-dimethoxy-2-cyclohexene(59415-76-8)

Safety Data

• Hazardous Substances Data: 59415-76-8(Hazardous Substances Data)

Upstream product

• 76152-75-5 cis-4-methoxycyclohex-2-ene-1-ol 
• 76152-75-5 trans-4-methoxycyclohex-2-ene-1-ol 
• 41513-32-0 trans-2-cyclohexene-1,4-diol 
• 74-88-4 methyl iodide 
• 86254-38-8 Carbonic acid (1S,4R)-4-methoxy-cyclohex-2-enyl ester methyl ester 
• 86254-38-8 Carbonic acid (1S,4S)-4-methoxy-cyclohex-2-enyl ester methyl ester 

Relevant articles and documents

Stereo- and Regioselective Palladium-Catalyzed 1,4-Dialkoxylation of Conjugated Dienes

A mild method for stereo- and regioselective 1,4-dialkoxylation of conjugated dienes was developed.The reaction is catalysed by palladium(II), and p-benzoquinone is used as the oxidant.It was found that the reaction rate depended on the presence of catalytic amounts of a strong acid.The role of the acid is probably 2-fold: (i) to create a cationic (?-allyl)palladium intermediate and (ii) to protonate the oxygen in the coordinated benzoquinone in the (?-allyl)palladium(benzoquinone) intermediate.