59467-08-2Relevant academic research and scientific papers
N,N-Dimethylformamide-protected Fe2O3 Combined with Pt Nanoparticles: Characterization and Catalysis in Alkene Hydrosilylation
Nagata, Tatsuki,Tanaka, Tatsuya,Lin, Xianjin,Kondo, Ryota,Suzuki, Takeyuki,Kanda, Yasuharu,Toyao, Takashi,Shimizu, Ken-ichi,Obora, Yasushi
, (2021/11/30)
We report a combination of N,N-dimethylformamide (DMF)-protected Fe2O3 nanoparticles (NPs) and Pt NPs for the hydrosilylation of various industrially relevant alkenes and tertiary silanes. The DMF-protected Fe2O3 and Pt NPs catalysts were characterized by transmission electron microscopy, X-ray absorption spectroscopy, and X-ray photoelectron spectroscopy. The catalyst of DMF-protected Fe2O3 NPs combined with Pt NPs can be recycled for five cycles by a simple extraction using hexane/DMF. The developed combination Fe2O3/Pt NPs catalyst is effective up to the 1-kilogram scale.
METHOD FOR PRODUCING ORGANIC SILICON COMPOUND USING RUTHENIUM NANOPARTICLE CATALYST
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Paragraph 0050; 0063-0064; 0076-0078, (2021/09/01)
PROBLEM TO BE SOLVED: To provide a method for efficiently producing an organic silicon compound by reacting an alkene with various hydrosilanes using a hydrosilylation catalyst that is free of platinum and can be recovered after a catalyst reaction. SOLUT
Highly selective hydrosilylation of olefins and acetylenes by platinum(0) complexes bearing bulky N-heterocyclic carbene ligands
Zak,Bo?t,Kubicki,Pietraszuk
supporting information, p. 1903 - 1910 (2018/02/17)
Platinum complexes bearing bulky N-heterocyclic carbene (NHC) ligands, i.e., [Pt(IPr?)(dvtms)] (where, IPr? = 1,3-bis{2,6-bis(diphenylmethyl)-4-methylphenyl}imidazol-2-ylidene) and [Pt(IPr?OMe)(dvtms)] (where, IPr?OMe = 1,3-bis{2,6-bis(diphenylmethyl)-4-m
INTAMOLECULAR CYCLIZATION MEDIATED BY SILYLMETALATION OF ACETYLENES WITH PhMe2SiMgMe/CuI AND RADICAL NATURE OF THE REAGENT
Okuda, Yasuhiro,Morizawa, Yoshitomi,Oshima, Koichiro,Nozaki, Hitosi
, p. 2483 - 2486 (2007/10/02)
Whereas CuI catalyzed silylmagnesation of the tosylate of 5-hexyn-1-ol with the title reagent affords dimethylphenylsilylmethylenecyclopentane exclusively, the mesylate of 3-butyn-1-ol gives a mixture of unexpected silylcyclobutene and cyclopropylidene derivative.
