59540-32-8Relevant academic research and scientific papers
α-hypervalent iodine functionalized phosphonium and arsonium ylides and their tandem reaction as umpolung reagents
Huang, Zhizhen,Yu, Xiaochun,Huang, Xian
, p. 8261 - 8264 (2002)
α-Hypervalent iodine functionalized phosphonium and arsonium ylides 2 can be used as umpolung ylides to react with nucleophiles to give α-heteroatom substituted ylides 4 in good yields. The nucleophilic substitution - Wittig tandem reaction of 2 can occur smoothly to provide an efficient method for the synthesis of (Z)-α-halo-α,β-unsaturated enoates or enones 6, stereoselectively.
An Efficient One Pot Synthesis of α-Iodo-α,β-unsaturated Esters, Ketones and Nitriles via Arsonium Salts
Huang, Yao-Zeng,Shi, Li-Lan,Li, Sao-Wei,Huang, Rong
, p. 2639 - 2646 (2007/10/02)
A number of α-iodo-α,β-unsaturated compounds 3 were synthesized under mild conditions via corresponding readily available arsonium salts 1 in one pot reaction.
