59552-59-9Relevant academic research and scientific papers
Selectivity in radical reactions of alanylglycine anhydride derivatives
Chai, Christina L.L.,Hay, Darren B.,King, Alison R.
, p. 605 - 610 (2007/10/03)
Functionalization of N,N′-disubstituted alanylglycine anhydrides under radical conditions is described. The radical (7), generated (i) from reactions of N,N′-disubstituted alanylglycine anhydrides with N-bromosuccinimide, and (ii) from related bromo compounds by reaction with tributyltin deuteride, undergoes carbon-bromine and carbon-deuterium bond formation with moderate to high diastereoselectivities depending on the N-substituents present.
