596100-76-4Relevant academic research and scientific papers
A green chemistry approach to a more efficient asymmetric catalyst: Solvent-free and highly concentrated alkyl additions to ketones
Jeon, Sang-Jin,Li, Hongmei,Walsh, Patrick J.
, p. 16416 - 16425 (2007/10/03)
There is a great demand for development of catalyst systems that are not only efficient and highly enantioselective but are also environmentally benign. Herein we report investigations into the catalytic asymmetric addition of alkyl and functionalized alk
Asymmetric addition of alkylzinc reagents to cyclic α,β-unsaturated ketones and a tandem enantioselective addition/diastereoselective epoxidation with dioxygen
Jeon, Sang-Jin,Walsh, Patrick J.
, p. 9544 - 9545 (2007/10/03)
Although over 100 catalysts have been reported to catalyze the asymmetric addition of alkyl groups to aldehydes, these catalysts fail to promote additions to ketones with >90% enantioselectivity. This paper describes the asymmetric 1,2-addition of alkyl g
