596101-13-2Relevant articles and documents
Asymmetric addition of alkylzinc reagents to cyclic α,β-unsaturated ketones and a tandem enantioselective addition/diastereoselective epoxidation with dioxygen
Jeon, Sang-Jin,Walsh, Patrick J.
, p. 9544 - 9545 (2003)
Although over 100 catalysts have been reported to catalyze the asymmetric addition of alkyl groups to aldehydes, these catalysts fail to promote additions to ketones with >90% enantioselectivity. This paper describes the asymmetric 1,2-addition of alkyl g