596106-76-2Relevant academic research and scientific papers
Chelating bis(thiophosphinic amidate)s as versatile supporting ligands for the group 3 metals. An application to the synthesis of highly active catalysts for intramolecular alkene hydroamination
Kim, Young Kwan,Livinghouse, Tom,Horino, Yoshikazu
, p. 9560 - 9561 (2007/10/03)
Bis(thiophosphinic amidate) complexes (i.e., 1) of representative group 3 and lanthanide metals have been quantiatively prepared in situ from the corresponding thiophosphinic amides and Ln[N(TMS)2]3. These unusual pentacoordinate complexes exhibit very high activity as catalysts for intramolecular alkene hydroamination. Copyright
