59611-34-6Relevant academic research and scientific papers
Zinc Bismuthate Zn(BiO3)2. I. A Useful Oxidizing Agent for the Efficient Oxidation of Organic Compounds
Firouzabadi, Habib,Mohammadpour-Baltork, Iraj
, p. 1131 - 1134 (2007/10/02)
Zinc bismuthate is an easily prepared and a stable compound.It could be used as an oxidant in organic solvents under aprotic or in the presence of a catalytic amount of a protic solvent.Primary and secondary saturated, allylic, and benzylic alcohols are converted to their carbonyl compounds in high yields.Mildness of the reagent is shown by the oxidation of thiols to their disulfides in excellent yields.Thioethers are also oxidized to their corresponding sulfoxides in good yields.
Barium Permanganate, Ba(MnO4)2; An Efficient and Mild Oxidizing Agent for Use Under Non-aqueous and Aprotic Conditions
Firouzabadi, H.,Mottghinejad, E.,Seddighi, M.
, p. 378 - 380 (2007/10/02)
Barium permanganate is used for the efficient oxidation of different types of alcohols and acyloins to the corresponding carbonyl compounds in boiling acetonitrile.The mildness of this reagent is shown by the oxidative S,S-coupling of several thiols to disulfides.
BIS(2,2'-BIPYRIDYL)COPPER(II) PERMANGANATE (BBCP): A MILD AND VERSATILE OXIDANT IN ORGANIC SYNTHESIS
Firouzabadi, H.,Sardarian, A. R.,Naderi, M.,Vessal, B.
, p. 5001 - 5004 (2007/10/02)
The preparation of bis(2,2'-bipyridyl)copper(II) permanganate (BBCP) is described.The reagent converts alcohols to the corresponding carbonyl compounds, α-hydroxy ketones to diketones, hydroquinone to p-benzoquinone, and compounds with benzylic double bonds to benzaldehyde in high yield.Benzophenone oxime, acetophenone oxime and various benzaldoximes are converted to the corresponding carbonyl compounds, aromatic amines to azo compounds, and benzylamine to benzaldehyde, usually in high yields, under mild condition.
TETRAKIS(PYRIDINE)SILVER DICHROMATE Py4Ag2Cr2O7 - A MILD AND EFFICIENT REAGENT FOR THE CONVERSION OF BENZYLIC AND ALLYLIC ALCOHOLS TO THEIR CORRESPONDING CARBONYL COMPOUNDS
Firouzabadi, H.,Sardarian, A.,Gharibi, H.
, p. 89 - 94 (2007/10/02)
Tetrakis(pyridine)silver dichromate is prepared and used for the oxidation of benzylic and allylic alcohols in refluxing benzene in high yields.
TRIS PARAPERIODATE 3 H2IO6, AN EFFICIENT AND A VERSATILE OXIDANT IN ORGANIC SYNTHESIS
Firouzabadi, H.,Iranpoor, N.,Hajipoor, G.,Toofan, J.
, p. 1033 - 1042 (2007/10/02)
Tris paraperiodate has been prepared and used for the oxidation of different classes of organic compounds in dry benzene with high yields.
CERIC TRIETHYLAMMONIUM NITRATE (NO3)6; AN EFFICIENT OXIDANT FOR THE OXIDATION OF BENZYLIC ALCOHOLS AND α-HYDROXY KETONES TO THEIR CORRESPONDING CARBONYL COMPOUNDS UNDER MILD CONDITIONS
Firouzabadi, H.,Iranpoor, N.
, p. 1143 - 1148 (2007/10/02)
Ceric triethylammonium nitrate is prepared and used for the oxidation of benzylic alcohols, and α-hydroxy ketones to their corresponding carbonyl compounds in methylene chloride with high yields.
BARIUM MANGANATE. A VERSATILE OXIDANT IN ORGANIC SYNTHESIS.
Firouzabadi,Mostafavipoor
, p. 914 - 917 (2007/10/02)
Preparation of barium manganate in large-scale is discussed. It is also shown that this reagent is capable of oxidizing organic substrates, converting alcohols to their corresponding carbonyl compounds, aromatic amines to their corresponding azo compounds, hydroquinone to p-benzoquinone, benzylamine to benzaldehyde, and triphenylphosphine to its oxide in good yields. Saturated hydrocarbons, unsaturated hydrocarbons, unsaturated ketones, and saturated amines are not affected by this reagent in a reasonable reaction time.
