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CAS

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596127-44-5

[Au2(μ-2-thiouracilato)(μ-bis(diphenylphosphino)methane)](CF3CO2) is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 596127-44-5 Structure

  • Basic information

    1. Product Name: [Au2(μ-2-thiouracilato)(μ-bis(diphenylphosphino)methane)](CF3CO2)
    2. Synonyms:
    3. CAS NO:596127-44-5
    4. Molecular Formula:
    5. Molecular Weight: 1018.49
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 596127-44-5.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: [Au2(μ-2-thiouracilato)(μ-bis(diphenylphosphino)methane)](CF3CO2)(CAS DataBase Reference)
    10. NIST Chemistry Reference: [Au2(μ-2-thiouracilato)(μ-bis(diphenylphosphino)methane)](CF3CO2)(596127-44-5)
    11. EPA Substance Registry System: [Au2(μ-2-thiouracilato)(μ-bis(diphenylphosphino)methane)](CF3CO2)(596127-44-5)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 596127-44-5(Hazardous Substances Data)

596127-44-5 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 596127-44-5 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 5,9,6,1,2 and 7 respectively; the second part has 2 digits, 4 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 596127-44:
(8*5)+(7*9)+(6*6)+(5*1)+(4*2)+(3*7)+(2*4)+(1*4)=185
185 % 10 = 5
So 596127-44-5 is a valid CAS Registry Number.

596127-44-5Downstream Products

596127-44-5Relevant articles and documents

Luminescence tribochromism and bright emission in gold(I) thiouracilate complexes

Lee, Young-A.,Eisenberg, Richard

, p. 7778 - 7779 (2003)

New dinuclear Au(I) complexes containing bridging thiouracilate and bis(diphenylphosphino)methane ligands have been synthesized and characterized structurally and spectroscopically. The compounds exhibit a unique behavior of solid-state luminescence tribochromism in which photoemission turns on upon gentle grinding of the sample and a sensitivity to pH in fluid solution. The emissive form in the solid state exhibits a bright blue or cyan emission upon irradiating at 375 nm. Structural studies show that the nonemissive form of the complexes has an extended helical ···Au···Au···Au··· structure in the solid with weak aurophilic interactions, whereas the blue emissive form has a strong intermolecular aurophilic interaction in the solid that leads to an arrangement of dimers of dinuclear (Au2) complexes. Interconversion between the two forms can be carried out by either recrystallization for solid-state samples or by exposure to vapors of volatile acid or base for fluid solutions of the complexes. Copyright

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