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Benzoyl chloride, 2,5-dibromo- is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 59615-13-3 Structure
  • Basic information

    1. Product Name: Benzoyl chloride, 2,5-dibromo-
    2. Synonyms:
    3. CAS NO:59615-13-3
    4. Molecular Formula: C7H3Br2ClO
    5. Molecular Weight: 298.361
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 59615-13-3.mol
  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: Benzoyl chloride, 2,5-dibromo-(CAS DataBase Reference)
    10. NIST Chemistry Reference: Benzoyl chloride, 2,5-dibromo-(59615-13-3)
    11. EPA Substance Registry System: Benzoyl chloride, 2,5-dibromo-(59615-13-3)
  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 59615-13-3(Hazardous Substances Data)

59615-13-3 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 59615-13-3 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 5,9,6,1 and 5 respectively; the second part has 2 digits, 1 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 59615-13:
(7*5)+(6*9)+(5*6)+(4*1)+(3*5)+(2*1)+(1*3)=143
143 % 10 = 3
So 59615-13-3 is a valid CAS Registry Number.

59615-13-3SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 15, 2017

Revision Date: Aug 15, 2017

1.Identification

1.1 GHS Product identifier

Product name 2,5-dibromobenzoyl chloride

1.2 Other means of identification

Product number -
Other names 2,5-Dibrom-benzoylchlorid

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:59615-13-3 SDS

59615-13-3Upstream product

59615-13-3Relevant articles and documents

Three-Dimensional Radical Covalent Organic Frameworks as Highly Efficient and Stable Catalysts for Selective Oxidation of Alcohols

Chen, Fengqian,Ding, Jiehua,Fang, Qianrong,Guan, Xinyu,Li, Hui,Qiu, Shilun,Tang, Bin,Valtchev, Valentin,Yan, Yushan,Zhu, Liangkui

, p. 22230 - 22235 (2021)

With excellent designability, large accessible inner surface, and high chemical stability, covalent organic frameworks (COFs) are promising candidates as metal-free heterogeneous catalysts. Here, we report two 3D radical-based COFs (JUC-565 and JUC-566) in which radical moieties (TEMPO) are uniformly decorated on the channel walls via a bottom-up approach. Based on grafted functional groups and suitable regular channels, these materials open up the application of COFs as highly efficient and selective metal-free redox catalysts in aerobic oxidation of alcohols to relevant aldehydes or ketones with outstanding turn over frequency (TOF) up to 132 h?1, which has exceeded other TEMPO-modified catalytic materials tested under similar conditions. These stable COF-based catalysts could be easily recovered and reused for multiple runs. This study promotes potential applications of 3D functional COFs anchored with stable radicals in organic synthesis and material science.

Synthesis of TEMPO radical decorated hollow porous aromatic frameworks for selective oxidation of alcohols

Shen, Yan-Ming,Xue, Yun,Yan, Mi,Mao, Hui-Ling,Cheng, Hu,Chen, Zhuo,Sui, Zhi-Wei,Zhu, Shao-Bin,Yu, Xiu-Jun,Zhuang, Jin-Liang

supporting information, p. 907 - 910 (2021/02/06)

A bottom-up approach was developed to prepare TEMPO radical decorated hollow aromatic frameworks (HPAF-TEMPO) by using TEMPO radical functionalized monomers and SiO2nanospheres as templates. The accessible inner layer, high density of TEMPO sites, and hybrid micro-/mesopores of the HPAF-TEMPO enable the aerobic oxidation of a broad range of alcohols with high efficiency and excellent selectivity.

Synthesis of Methoxy-, Methylenedioxy-, Hydroxy-, and Halo-Substituted Benzophenanthridinone Derivatives as DNA Topoisomerase IB (TOP1) and Tyrosyl-DNA Phosphodiesterase 1 (TDP1) Inhibitors and Their Biological Activity for Drug-Resistant Cancer

Hu, De-Xuan,Tang, Wen-Lin,Zhang, Yu,Yang, Hao,Wang, Wenjie,Agama, Keli,Pommier, Yves,An, Lin-Kun

, p. 7617 - 7629 (2021/06/25)

As a recently discovered DNA repair enzyme, tyrosyl-DNA phosphodiesterase 1 (TDP1) removes topoisomerase IB (TOP1)-mediated DNA protein cross-links. Inhibiting TDP1 can potentiate the cytotoxicity of TOP1 inhibitors and overcome cancer cell resistance to

Structure-Activity Studies Reveal Scope for Optimisation of Ebselen-Type Inhibition of SARS-CoV-2 Main Protease

Brewitz, Lennart,Choudhry, Hani,Malla, Tika R.,Salah, Eidarus,Schofield, Christopher J.,Suits, Timothy F.,Thun-Hohenstein, Siegfried T. D.,Tumber, Anthony

supporting information, (2021/12/30)

The reactive organoselenium compound ebselen is being investigated for treatment of coronavirus disease 2019 (COVID-19) and other diseases. We report structure-activity studies on sulfur analogues of ebselen with the Severe Acute Respiratory Syndrome coronavirus 2 (SARS-CoV-2) main protease (Mpro), employing turnover and protein-observed mass spectrometry-based assays. The results reveal scope for optimisation of ebselen/ebselen derivative- mediated inhibition of Mpro, particularly with respect to improved selectivity.

Stereoinvertive C–C Bond Formation at the Boron-Bound Stereogenic Centers through Copper-Bipyridine-Catalyzed Intramolecular Coupling of α-Aminobenzylboronic Esters

Suginome, Michinori,Yamamoto, Takeshi,Yoshinaga, Yukako

supporting information, p. 7251 - 7255 (2020/03/23)

Enantiospecific intramolecular Suzuki–Miyaura-type coupling with α-(2-halobenzoylamino)benzylboronic esters to give 3-substituted isoindolinones is achieved by using copper catalysts with 2,2′-bipyridine-based achiral ligands. Enantioenriched α-aminobenzylboron reactants bearing a hydrogen atom at the boron-bound stereogenic carbons undergo stereoinvertive coupling in the presence of a 6-phenyl-2,2′-bipyridine ligand with high enantiospecificity. α-Aminobenzylboronates bearing fully substituted boron-bound stereogenic centers also gave the 3,3-disubstituted isoindolinones with stereospecific stereochemical inversion in the presence of simple 2,2′-bipyridine as a ligand.

Organocatalyst in Direct C(sp2)-H Arylation of Unactivated Arenes: [1-(2-Hydroxyethyl)-piperazine]-Catalyzed Inter-/Intra-molecular C-H Bond Activation

Yadav, Lalit,Tiwari, Mohit K.,Shyamlal, Bharti Rajesh Kumar,Chaudhary, Sandeep

, p. 8121 - 8141 (2020/07/16)

This article describes the identification of 1-(2-hydroxyethyl)-piperazine as a new, cost-effective, highly efficient organocatalyst, which promotes both inter- A nd intra-molecular direct C(sp2)-H arylations of unactivated arenes in the presence of potassium tert-butoxide. While the inter-molecular C-H arylation of unactivated benzenes with aryl halides (Ar-X; X = I, Br, Cl) toward biaryl syntheses underwent smoothly in the presence of only 10 mol percent organocatalyst, the intra-molecular C-H arylation catalytic system composed of 40 mol percent each of the catalyst and the additive (4-dimethylaminopyridine (DMAP)). The novel catalyst was also able to perform both inter- A nd intra-molecular direct arylations simultaneously in a single pot. The mechanistic studies confirmed the involvement of aryl radical anions and proceeded via a single-electron-transfer (SET) mechanism. The large substrate scope, high functional group tolerance, competition experiments, gram-scale synthesis, and kinetic studies further highlight the importance and versatile nature of the methodology as well as the compatibility of the new catalyst. To the best of our knowledge, this is the first report on any organocatalyst that reported detailed investigations of both inter- A nd intra-molecular direct C(sp2)-H arylations of unactivated arenes in a single representation.

Rational design of thermally activated delayed fluorescence emitters with aggregation-induced emission employing combined charge transfer pathways for fabricating efficient non-doped OLEDs

Ma, Fulong,Cheng, Yu,Zheng, Yu,Ji, Hefang,Hasrat, Kamran,Qi, Zhengjian

, p. 9413 - 9422 (2019/08/08)

The development of luminescent materials simultaneously possessing thermally activated delayed fluorescence (TADF), aggregation-induced emission (AIE), and high luminescence efficiency in the solid state is urgent for fabricating efficient non-doped organ

Facile synthesis of 1-naphthols through a copper-catalyzed arylation of methyl ketones with o-bromoacetophenones

Lou, Zhen-Bang,Pang, Xin-Long,Chen, Chao,Wen, Li-Rong,Li, Ming

supporting information, p. 1231 - 1235 (2015/12/30)

The coupling reactions of simple methyl ketones with o-bromoacetophenones and subsquential cyclization reactions were realized to produce a range of 1-naphthols. These cascade reactions were initiated by a rare Cu-catalyzed arylation reaction of methyl ketones with aromatic bromides.

High Fluorescence Efficiencies and Large Stokes Shifts of Folded Fluorophores Consisting of a Pair of Alkenyl-Tethered, π-Stacked Oligo-p-phenylenes

He, Bairong,Nie, Han,Chen, Long,Lou, Xiaoding,Hu, Rongrong,Qin, Anjun,Zhao, Zujin,Tang, Ben Zhong

supporting information, p. 6174 - 6177 (2016/01/09)

A series of pure hydrocarbon fluorophores containing a pair of π-stacked oligo-p-phenylenes have been synthesized and analyzed by NMR and X-ray crystallography. They show good fluorescence in solutions and enhanced fluorescence in the aggregated state. Large Stokes shifts (up to 214 nm) have been achieved in these folded fluorophores in virtue of intramolecular energy transfer, and balanced structural rigidity and flexibility. These folded fluorophores provide perfect models for understanding the energy and charge transfer process in π-stacked systems.

Synthesis and characterization of solution-processable ladderized n-type naphthalene bisimide copolymers for OFET applications

Durban, Matthew M.,Kazarinoff, Peter D.,Segawa, Yukari,Luscombe, Christine K.

experimental part, p. 4721 - 4728 (2012/05/20)

Solution-processable n-type ladder-based polymers are highly desirable due to their potential capability to form strong π-π interactions. A series of 5 highly soluble naphthalene diimide (NDI) polymers are presented, differing in the degree to which they

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