59639-96-2

Basic information

• Product Name: N-Allyllmethanesulfonamide
• Synonyms: N-Allyllmethanesulfonamide;N-Allyllmethylnesulfonamide;N-allylmethanesulfonamide
• CAS NO: 59639-96-2
• Molecular Formula: C₄H₉NO₂S
• Molecular Weight: 135.18476
• Mol File: 59639-96-2.mol
• Article Data: 1

Chemical Properties

• Appearance: white powder
• Storage Temp.: 2-8°C
• CAS DataBase Reference: N-Allyllmethanesulfonamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-Allyllmethanesulfonamide(59639-96-2)
• EPA Substance Registry System: N-Allyllmethanesulfonamide(59639-96-2)

Safety Data

• Hazardous Substances Data: 59639-96-2(Hazardous Substances Data)

Usage

General Description

N-Allyl methanesulfonamide is a chemical compound that belongs to the class of sulfonamides and contains an allyl functional group. It is commonly used in organic synthesis and as a building block for the creation of various other compounds. N-Allyl methanesulfonamide has been studied for its potential applications in the pharmaceutical industry, particularly in the development of new drugs. It possesses unique properties that make it a valuable precursor in the synthesis of biologically active molecules. Additionally, it is known for its strong nucleophilicity, and it can act as a Michael donor in a variety of organic reactions. Overall, N-Allyl methanesulfonamide is a versatile and important chemical with various potential applications in the field of organic chemistry and drug development.

Upstream product

• 145429-75-0 N-allyl-N-benzylmethanesulfonamide 

Downstream Products

• 1309862-01-8 N-allyl-N-(phenylethynyl)methanesulfonamide 
• 1638755-34-6 N-((2-(methoxy(naphthalen-1-yl)methyl)phenyl)ethynyl)-4-methyl-Nphenylbenzenesulfonamide 
• 1638755-31-3 N-allyl-N-((2-((allyloxy)(phenyl)methyl)phenyl)ethynyl)methanesulfonamide 
• 1638755-28-8 N-allyl-N-((4-fluoro-2-(methoxy(phenyl)methyl)phenyl)ethynyl)methanesulfonamide 
• 1638755-19-7 N-allyl-N-((2-(methoxy(phenyl)methyl)phenyl)ethynyl)methanesulfonamide 
• 1227797-14-9 N-(3-(4-acetylphenyl)propyl)methanesulfonamide 
• 1011486-82-0 C₁₅H₁₇IN₂O₄S 

Relevant articles and documents

Metal-free reductive cleavage of C-N and S-N bonds by photoactivated electron transfer from a neutral organic donor

A photoactivated neutral organic super electron donor cleaves challenging arenesulfonamides derived from dialkylamines at room temperature. It also cleaves a)ArC-NR and b)ArN-C bonds. This study also highlights the assistance given to these cleavage reactions by the groups attached to N in (a) and to C in (b), by lowering LUMO energies and by stabilizing the products of fragmentation. Radical fragmentations: Electron transfer from the photoactivated neutral electron donor 1 delivers high yields of S-N and C-N cleavage products for a range of nitrogen-containing species. These reactions proceed at room temperature and under mild reaction conditions in the absence of any metal reagents. DMF=N,N-dimethylformamide, Ts=4-toluenesulfonyl.