596815-70-2Relevant academic research and scientific papers
Pd0-catalyzed coupling cyclization reaction of aryl or 1-alkenyl halides with 1,2-allenyl ketones: Scope and mechanism. An efficient assembly of 2,3,4-, 2,3,5-tri- and 2,3,4,5-tetrasubstituted furans
Ma, Shengming,Zhang, Junliang,Lu, Lianghua
, p. 2447 - 2456 (2003)
Described herein is the Pd0-catalyzed coupling cyclization reaction of 1,2-allenyl ketones with organic halides leading efficiently and conveniently to not only 2,3,4- and 2,3,5-trisubstituted furans but also 2,3,4,5-tetrasubstituted furans. Fu
Studies on K2CO3-Catalyzed 1,4-Addition of 1,2-Allenic Ketones with Diethyl Malonate: Controlled Selective Synthesis of β,γ-Unsaturated Enones and α-Pyrones
Ma, Shengming,Yu, Shichao,Yin, Shaohu
, p. 8996 - 9002 (2007/10/03)
The K2CO3 (10 mol%)-catalyzed 1,4-addition reaction of diethyl malonate with various substituted 1,2-allenic ketones leading to polyfunctionalized β,γ-unsaturated enones 3 or 4 was studied. With 3-unsubstituted 1-substituted-1,2-alle
