59744-44-4Relevant academic research and scientific papers
Magnesium dicarboxylates promote the prenylation of phenolics that is extended to the total synthesis of icaritin
Fu, Xuewen,Lu, Xiaoxia,Wang, Chun,Wen, Yongju,Xiong, Wei,Zhang, Guolin,Zhang, Jichao
, p. 1117 - 1124 (2022/02/16)
The prenylation of phenolic substrates promoted by magnesium dicarboxylates was developed. An investigation of the scope demonstrated that substrates with electron-donating group(s) gave better yields than those with electron-withdrawing group(s). Althoug
Prenylation of aromatics. Lithium-ammonia reduction of o-silylated tertiary cinnamyl alcohols
Ballester, Pablo,Capo, Magdalena,Saa, Jose M.
, p. 1339 - 1342 (2007/10/02)
Silyl protected phenolic or non-phenolic tertiary cinnamyl alcohols undergo metalammonia induced hydrogenolysis with concomitant double bond isomerization, thus providing a unique entrance to prenyl substituted aromatics. Chiral alcohols yielded E:Z mixtu
