598-60-7Relevant articles and documents
Process for the preparation of penem compounds and intermediates for this preparation
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, (2008/06/13)
Compounds of the general formula I in which, X denotes a halogen atom;, Y denotes a hydrogen atom, a halogen atom, or a moiety of the general formula II Z denotes a halogen atom, a hydroxy group, a substituted hydroxy group, an -S(O)nR5 group, or an -Se(O)mR5 group;, n denotes 0, 1 or 2, preferably 0 or 1;, m denotes 0 or 1;, R3 denotes a hydrogen atom or an organic group;, R4 denotes a hydrogen atom, a carboxy-salt-forming ion, or a carboxy-ester-forming group;, R5 denotes a hydrogen atom, a hydrocarbon group, or a heterocyclyl group; and, R12 denotes a hydrogen atom, an unsubstituted or substituted hydrocarbon group, or an unsubstituted or substituted heterocyclyl group;, are novel intermediates useful in the preparation of 6-methylene-penems of the general formula X: