59805-79-7

Basic information

• Product Name: (+)-3-[2-(2,2,6-Trimethylcyclohexylidene)ethyl]furan
• Synonyms: (+)-3-[2-(2,2,6-Trimethylcyclohexylidene)ethyl]furan;Microcionin-3
• CAS NO: 59805-79-7
• Molecular Formula: C15H22O
• Molecular Weight: 218.33
• Mol File: 59805-79-7.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: (+)-3-[2-(2,2,6-Trimethylcyclohexylidene)ethyl]furan(CAS DataBase Reference)
• NIST Chemistry Reference: (+)-3-[2-(2,2,6-Trimethylcyclohexylidene)ethyl]furan(59805-79-7)
• EPA Substance Registry System: (+)-3-[2-(2,2,6-Trimethylcyclohexylidene)ethyl]furan(59805-79-7)

Safety Data

• Hazardous Substances Data: 59805-79-7(Hazardous Substances Data)

Upstream product

• 22037-28-1 3-bromofurane 
• 128671-68-1 2-[2-Bromo-eth-(E)-ylidene]-1,1,3-trimethyl-cyclohexane 

Relevant articles and documents

New aspects in the synthesis of mono- and dialkylfurans

3-substituted furan systems can be obtained by alkylation of 3-lithium furans with various electrophiles in the presence of hexamethylphosphoric acid triamide in good yields. The 2- or 5-position of 3-methyl furan is blocked with high regio selectivity by silylation. After metalation and alkylation of the remaining free α-position and subsequent desilylation the 2,3- and 2,4-disubstituted furans are obtained. These methods are used to synthesize the naturally occuring compounds ursinanolide (2) and longifolin (4).