59848-65-6Relevant academic research and scientific papers
Heteropoly acid catalysts in Prins cyclization for the synthesis of Florol
de Meireles, Augusto L.P.,da Silva Rocha, Kelly A.,Kozhevnikova, Elena F.,Kozhevnikov, Ivan V.,Gusevskaya, Elena V.
, (2021)
H3PW12O40 heteropoly acid supported on SiO2 and its bulk acidic cesium salt Cs2.5H0.5PW12O40 are demonstrated to be highly active and recyclable solid catalysts for Pr
PRODUCTION OF 2-SUBSTITUTED 4-METHYL-TETRAHYDROPYRANS FROM STARTING MATERIALS CONTAINING 2-ALKYL-4,4-DIMETHYL-1,3-DIOXANES
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Paragraph 0257, (2017/04/13)
The invention relates to a method for producing 2-substituted 4-methyltetrahydropyrans of general formula (I) from starting materials containing at least one 2-substituted 4,4-dimethyl-1,3-dioxane of general formula (II).
1,2-ELIMINATION OF ALCOHOL FROM HOMOALLYL ETHERS UNDER THE INFLUENCE OF MIXED METAL BASES
Margot, Christian,Rizzolio, Michele,Schlosser, Manfred
, p. 2411 - 2424 (2007/10/02)
Lithium diisopropylamide in the presence of catalytic amounts of potassium tert-butoxide smoothly converts homoallyl or homobenzyl type ethers to dienes (e.g., 1, 3, 5, 26) or styrenes (2). γ,δ-Unsaturated acetals give 1,3-dienyl ethers (e.g., 4) and 4-alkylidenetetrahydropyrans or dihydropyrans produce a variety of dienols (e.g., 6 - 17, 20 - 22). - If there is a choice, the new double bond is formed with high trans-selectivity while the configuration of existing double bonds is retained. - The elimination mode is syn-periplanar and concerted, though E1cb like.
REACTIONS ON A SURFACE. 1. CONDENSATION OF 3-METHYL-3-BUTEN-1-OL WITH CARBONYL COMPOUNDS ON SiO2 AND Al2O3
Ibatullin, U. G.,Pavlov, Yu. V.,Safarov, M. G.
, p. 1107 - 1109 (2007/10/02)
3-Methyl-3-buten-1-ol reacts with various aldehydes and ketones on silica gel and Al2O3 surfaces in the absence of solvents and conventional catalysts for this reaction to form derivatives of di- and tetrahydropyrans.
SYNTHESIS OF SUBSTITUTED 5,6- AND 3,6-DIHYDRO-2H-PYRANS BY ACID CONDENSATION OF ISOBUTYLENE AND α-METHYLSTYRENE WITH ALIPHATIC ALDEHYDES
Romanov, N. A.,Kantor, E. A.,Karakhanov, R. A.,Rakhmankulov, D. L.
, p. 351 - 354 (2007/10/02)
2,4-Disubstituted dihydropyrans, isomeric with respect to the position of the double bond, were obtained by the reaction of isobutylene and α-methylstyrene with formaldehyde and aliphatic aldehydes.
PRODUCTION OF SUBSTITUTED 5,6- AND 3,6-DIHYDRO-2H-PYRANS FROM 4,4-DIMETHYL- AND 4-METHYL-4-PHENYL-1,3-DIOXANES AND CARBONYL COMPOUNDS
Romanov, N. A.,Kantor, E. A.,Musavirov, R. S.,Karakhanov, R. A.,Rakhmankulov, D. L.
, p. 1576 - 1581 (2007/10/02)
2,4-Disubstituted and 2,2,4-trisubstituted dihydropyrans, isomeric with respect to the position of the double bond, were obtained by the reaction of 4,4-dimethyl- and 4-methyl-4-phenyl-1,3-dioxanes with aldehydes and ketones.The effects of temperature and of the amount and nature of the catalyst on the direction and selectivity of the reaction were investigated.
