5987-55-3

Basic information

• Product Name: Methyl-β-L-arabinosid-(3,4-phenylboronat)
• CAS NO: 5987-55-3
• Molecular Weight: 250.059
• Mol File: 5987-55-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Methyl-β-L-arabinosid-(3,4-phenylboronat)(CAS DataBase Reference)
• NIST Chemistry Reference: Methyl-β-L-arabinosid-(3,4-phenylboronat)(5987-55-3)
• EPA Substance Registry System: Methyl-β-L-arabinosid-(3,4-phenylboronat)(5987-55-3)

Safety Data

• Hazardous Substances Data: 5987-55-3(Hazardous Substances Data)

Upstream product

• 3262-89-3 triphenylboroxine 
• 91-09-8 methyl β-L-arabinopyranoside 
• 5328-63-2 methyl-β-D-arabinopyranoside 
• 98-80-6 phenylboronic acid 

Relevant articles and documents

Complexation-induced activation of sugar OH groups. Regioselective alkylation of methyl fucopyranoside via cyclic phenylboronate in the presence of amine

Methyl fucopyranoside undergoes highly regioselective 3-O-alkylation via complexation with phenylboronic acid, followed by treatment of the resulting 3,4-boronate with iodobutane in the presence of a tertiary amine and Ag2O. The essential step is suggested to be regioselective activation of the 3-O nucleophilic center upon amine coordination with the O-bonded boron atom.