59875-95-5

Basic information

• Product Name: 1,3-Propanedione, 1,3-diphenyl-2-propyl-
• CAS NO: 59875-95-5
• Molecular Formula: C18H18O2
• Molecular Weight: 266.34
• Mol File: 59875-95-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1,3-Propanedione, 1,3-diphenyl-2-propyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3-Propanedione, 1,3-diphenyl-2-propyl-(59875-95-5)
• EPA Substance Registry System: 1,3-Propanedione, 1,3-diphenyl-2-propyl-(59875-95-5)

Safety Data

• Hazardous Substances Data: 59875-95-5(Hazardous Substances Data)

Upstream product

• 107-08-4 1-iodo-propane 
• 120-46-7 1,3-diphenylpropanedione 
• 3240-29-7 1-Phenylpent-4-en-1-one 
• 100-51-6 benzyl alcohol 

Downstream Products

• 1229927-43-8 (2,2'-bipyridine)bis(2-n-propyl-1,3-diphenyl-1,3-propanedionato)nickel(II) 
• 1229927-45-0 (1,10-phenanthroline)bis(2-n-propyl-1,3-diphenyl-1,3-propanedionato)nickel(II) 
• 47074-06-6 2-Methyl-1,5-diphenyl-1,5-pentanedione 

Relevant articles and documents

Redox-triggered ruthenium-catalyzed remote C?H acylation with primary alcohols

Redox-triggered metal-catalyzed cross-coupling reactions from readily available alcohols provide a step economical means to synthesize ketones and related compounds. Prior examples for hydrogenative remote C(sp3)?H functionalization of olefins via a metal walking process featured external reducing agents. Here, we report a strategy for redox-triggered hydrogenative remote C(sp3)?H acylation of olefins with primary alcohols both as an acylating agent and a reductant, which is validated by the base-free 1,3-diketone synthesis. Mechanistic studies have confirmed that the reaction takes place via an aldehyde intermediate and a metal walking process.