59892-26-1Relevant academic research and scientific papers
Reaction of metal alkoxides with 3-alkyl-substituted acetylacetone derivatives - Coordination vs. hydrodeacylation
Puchberger, Michael,Rupp, Wolfgang,Bauer, Ulrike,Schubert, Ulrich
, p. 1289 - 1294 (2007/10/03)
Reaction of Ti(OiPr)4 or Zr(OPr)4 with 1 or 2 molar equiv of the 3-alkyl-substituted acetylacetone derivatives 3-acetyl-6-trimethoxysilylhexane-2-one or 3-acetylpentane-2-one not only gives the corresponding β-diketonate complexes but also results in about 15% hydrodeacylation of the β-diketone. With the stronger Lewis acid Al(O sBu)3 hydrodeacylation prevails. Hydrodeacylation is suppressed when a 1:5 ratio of metal alkoxide and β-diketone is reacted.
