59941-98-9Relevant articles and documents
N-Heterocyclic Carbene-Catalyzed Truce-Smiles Rearrangement of N-Arylacrylamides via the Cleavage of Unactivated C(aryl)-N Bonds
Yasui, Kosuke,Kamitani, Miharu,Fujimoto, Hayato,Tobisu, Mamoru
supporting information, p. 1572 - 1576 (2021/03/03)
We report on the N-heterocyclic carbene (NHC)-catalyzed Truce-Smiles rearrangement of aniline derivatives, in which an unactivated C(aryl)-N bond is cleaved, leading to the formation of a new C(aryl)-C bond. The key to the success of this reaction is the