59973-08-9Relevant academic research and scientific papers
A Novel Catalyst System, Trimethylsilyl Chloride and Indium(III) Chloride, as an Efficient Catalyst in the Sulfide Synthesis
Mukaiyama, Teruaki,Ohno, Takashi,Nishimura, Takashi,Han, Jeong Sik,Kobayashi, Shu
, p. 2524 - 2527 (2007/10/02)
O-Trimethylsilyl monothioacetals, which are generally difficult to activate under acidic conditions due to their rapid disproportionation, smoothly react with triethylsilane in the presence of a novel catalyst system, trimethylsilyl chloride and indium(III) chloride, to afford the corresponding sulfides in good to high yields.One pot synthesis of sulfides from aldehydes is also attained in high yields by successive treatment of aldehydes with trimethylsilyl alkyl (aryl) sulfides and triethylsilane in the presence of the above catalyst system under extremely mild conditions.
An Effective Activation of O-Trimethylsilyl Monothioacetal under Extremely Mild Conditions Using a Novel Catalyst System, Trimethylsilyl Chloride and Indium(III) Chloride
Mukaiyama, Teruaki,Ohno, Takashi,Nishimura, Takashi,Han, Jeong Sik,Kobayashi, Shu
, p. 2239 - 2242 (2007/10/02)
A novel catalyst system, trimethylsilyl chloride and indium(III) chloride, effectively catalyzes the reaction of O-trimethylsilyl monothioacetals with triethylsilane and silylated carbon nucleophiles, respectively, to afford the corresponding sulfide derivatives in good to high yields.
