59999-02-9Relevant academic research and scientific papers
A New Group of Compounds Derived from Nereistoxin - Synthesis of Bis-dimethylamino-tris-disulfanes
Muehlstaedt, M.,Heinicke, J.,Schubert H.
, p. 841 - 847 (2007/10/02)
The reaction of organo-thiosulfates, BUNTE-salts, with mercaptans is a convenient synthesis of disulfanes.Similarly bis-BUNTE-salt 7 and tert. butyl mercaptan give bis-disulfane 5c.By treating 7 with several aliphatic mercaptans we found the formation of the tris-disulfanes 8a-d in preparative amounts in addition to the bis-disulfanes 5a-d expected.This reaction was investigated.The preparation of the compounds 8 is described and a proposal is given for a mechanism of the formation of 8 as a thiol-disulfide-interchange.
