6002-42-2Relevant academic research and scientific papers
Reductive cleavage of the halogen-phosphorus and sulfur-phosphorus bonds with alkali metals
Stankiewicz, Marek,Nycz, Jacek,Rachon, Janusz
, p. 330 - 339 (2002)
The reduction of thiophosphorus acid chlorides with alkali metals (Na, K) in liq. NH3/THF solution, potassium anthracenide, and potassium napththalenide was investigated. It was found that these types of phosphorus compounds easily undergo reduction to 〉P-S- anions. It was also demonstrated that 〉P-O- and 〉P-S- anions as well very efficiently undergo sulfurization with elementary sulfur in liquid ammonia to yield 〉P(O)S- and 〉P(S)S- anions, respectively.
