60025-44-7Relevant academic research and scientific papers
Expedient synthesis of gem-dialkylbenzyl heterocycles through olefinic hydroarylation
Lian, Yajing,Burford, Kristen,Londregan, Allyn T.
, p. 9509 - 9514 (2015)
A robust approach to gem-dialkylbenzyl heterocycles has been developed through a triflic acid-catalyzed hydroarylation of olefinic heterocycles. A broad range of substrates containing pyridine, quinoline, pyrazole, triazole and imidazole moieties are shown to be highly compatible with this method. This rapid construction of gem-dialkyl groups should be useful in the synthesis of drug-like molecules containing heterocyclic diversity and in the study of the gem-dialkyl effect.
HETEROLEPTIC CYCLOMETALLATED IR(III) COMPLEXES HAVING A CYCLOMETALLATED 6-MEMBERED RING
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Paragraph 0106, (2014/02/16)
Heteroleptic cyclometallated complexes having a 6-membered ring cyclometallated to the metal, as shown in Formula (I), are provided: wherein ring A and ring B are each independently a 5 or 6-membered carbocyclic or heterocyclic ring; wherein L1 /sub
